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1 article(s) from Lee, Hai Whang

Kinetics and mechanism of the anilinolysis of aryl phenyl isothiocyanophosphates in acetonitrile

Hasi Rani Barai and
Hai Whang Lee

Beilstein J. Org. Chem. 2013, 9, 615–620, doi:10.3762/bjoc.9.68

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Graphical Abstract

Scheme 1: Reactions of Y-aryl phenyl isothiocyanophosphates (1a–e) with XC₆H₄NH₂(D)₂ in MeCN at 55.0 °C.

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Figure 1: Brönsted plots with X [log k_H versus pK_a(X)] of the reactions of Y-aryl phenyl isothiocyanophosphat...

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Figure 2: Plots of ρ_X versus σ_Y and ρ_Y versus σ_X of the reactions of Y-aryl phenyl isothiocyanophosphates wit...

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Scheme 2: Backside attack involving in-line-type TSb and frontside attack involving a hydrogen-bonded, four-c...

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Scheme 3: Backside attack involving a hydrogen-bonded, four-center-type TSb-H.

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Full Research Paper

Published 26 Mar 2013

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